Atomic Layer Deposition Synthesis and Photoelectrochemical Charge Behavior in Tungsten, Iron, and Titanium Oxide Heterostructures

Abstract

This thesis explores new approaches to synthesizing and understanding photoanodes for water splitting. By tuning materials' mophology on the nanoscale, their ability to absorb light energy and efficiently convert it in to chemical energy is improved. This is evident by an increase in photocatalytic efficiency and can be demonstrated with visible light sensitive catalysts. Production of these materials involved the development of alternative synthesis routes for traditional water splitting catalysts. Our hypothesis is further supported by probing charge dynamics using microwave reflectivity measurements, which show that the lifetime of charges in these new nanostructures is optimized.